Volume 250
Main Index

Issue 1, Pages 1-638 (5 July 1983)

Editorial note Page v

Formation of a fulvene by trimerisation of an alkyne at a rhodium centre; crystal structure of cycloocta-1,5-diene(η5-1,3,6-tri-t-butylfulvene) rhodium hexafluorophosphate Pages c15-c20 Grainne Moran, Michael Green, A. Guy Orpen

Arene substitution by iridium complexes under mild conditions Pages c25-c27 Kiyoshi Isobe, Amelio Vázquez de Miguel, Peter M. Maitlis

Alkylations allyliques catalysees au nickel Pages c21-c24 Therese Cuvigny, Marc Julia

A new method for the preparation of some carbonyl metalate anions Pages c33-c35 Fausto Calderazzo, Guido Pampaloni

Pentamethylcyclopentadienylcopper: A metal ligand fragment isolobal with methylene Pages c28-c32 Gabino A. Carriedo, Judith A. K. Howard, F. Gordon A. Stone

Metallacyclobutadiene complexes from ligand combination of cs and acetylene on osmium Pages c5-c8 G. P. Elliott, W. R. Roper

Octafluorocyclooctatetraene transition metal compounds: displacement of fluoride by metal carbonyl anions Pages c1-c4 Stephen J. Doig, Russell P. Hughes, Steven L. Patt, Deborah E. Samkoff, Wayne L. Smith

Routes to optically active electron-rich olefins (L*2 and some derived carbenemetal complexes; x-ray structures of [Co(CO)(L*)(NO(PPh3)] and cis-[Rh(Cl)(COD)(L′*)][L*= (S)-Me, Pages c9-c14 Anthony W. Coleman, Peter B. Hitchcock, Michael F. Lappert, Robin K. Maskell, Joachim H. Müller

Author index Pages c35-c36

Hydrometallation of 1-octene with grignard reagents. Alkylmagnesiums and alkylmagnesium hydrides catalyzed by dicyclopentadienyltitanium dichloride Pages 1-12 E. C. Ashby, Richard D. Ainslie

Organoboranes : XXVIII. Convenient procedures for the synthesis of borinane Pages 13-22 Herbert C. Brown, Ganesh G. Pai

Organoboron compounds : CDV. Bromination of 2-isopropyl-2-boraadamantane Pages 23-31 B. M. Mikhailov, T. A. Shchegoleva, E. M. Shashkova, V. G. Kiselev

Beiträge zur chemie des bors : 132. 1-phospha- und 1-arsa-4-bora-cyclohexadiene-2,5 Pages 33-48 Hans-Otto Berger, Heinrich Nöth

Stable 1,4-diaza-1,3-butadiene(α-diimine)-zinc and -aluminium radicals formed in single electron transfer reactions: their consequences for organic syntheses Pages 49-61 Gerard Van Koten, Johann T. B. H. Jastrzebski, Kees Vrieze

Kinetic and stereochemical factors in the hydralumination of alkenes and the configurational stability of the resulting carbon---aluminum bond Pages 63-81 John J. Eisch, Kennetih C. Fichter

Reaction of organo-thallium(III) and -mercury(II) compounds with nitronate ion and N-benzyl-1,4-dihydronicotinamide: reductive electron-transfer activation of the metal---carbon bond toward homolysis Pages 83-97 Hideo Kurosawa, Hiroshi Okada, Masahiro Sato, Tatsuaki Hattori

Conversion of disilanes to functional monosilanes : XII. The palladium(0)-catalyzed dechlorinative silylation of benzylic chlorides with methylchlorodisilanes. A facile route to benzylmethylchlorosilanes Pages 99-107 Hideyuki Matsumoto, Miyuki Kasahara, Ikuya Matsubara, Masatoshi Takahashi, Takeshi Arai, Minoru Hasegawa, Taichi Nakano, Yoichiro Nagai

Chemistry of siloles. The reactions of siloles with organolithium reagents Pages 109-119 Mitsuo Ishikawa, Tatsuru Tabohashi, Hiroshi Sugisawa, Kunio Nishimura, Makoto Kumada

Siloxycyclopropanes. Useful synthetic intermediates Pages 121-133 Shinji Murai, Ilhyong Ryu, Noboru Sonoda

Reactivity of thallium tris[tris(pentafluorophenyl)germyl] mercurate Pages 135-143 G. A. Razuvaev, M. N. Bochkarev, L. V. Pankratov

The role of ion pairs in SE reactions of organometallic compounds Pages 145-156 O. A. Reutov

Solvent effects on the rates and mechanisms of organotin alkyl exchange reactions Pages 157-170 Valery S. Petrosyan

2,2-diphenyl-2λ5-phospha-phenalenyl-und 2,2-dimethyl-2λ5-phospha-indenyl-lithium Pages 171-182 Hubert Schmidbaur, Albert Mörtl

Structural correlations and NMR properties of mononuclear cyclic triphosphorus complexes Pages 183-195 M. Di Vaira, L. Sacconi, P. Stoppioni

Capto-dative substituent effects : XIII. C4-bridged radical dimerisation with α-phenylselenoacrylic acid derivatives Pages 197-202 Z. Janousek, S. Piettre, F. Gorissen-Hervens, H. G. Viehe

Oxytelluration of olefins to (β-alkoxy- and β-hydroxy-alkyl)aryltellurium dihalides and their reactions with reducing agents and aqueous NaOH Pages 203-215 Sakae Uemura, Shin-Ichi Fukuzawa, Akio Toshimitsu

Recent advances in organolanthanide chemistry Pages 217-226 William J. Evans

Some organic reactions promoted by samarium diiodide Pages 227-236 J. Souppe, L. Danon, J. L. Namy, H. B. Kagan

Actinide-centered cyclometalation chemistry. An unusually distorted thorium bishydrocarbyl: Thp[η5-(CH3)5C5]2CH2Si(CH3)3]2 Pages 237-246 Joseph W. Bruno, Tobin J. Marks, Victor W. Day

An ESR study of the photolysis of dicyclopentadienyltitanium dichloride Pages 247-256 Peter B. Brindley, Alwyn G. Davies, Jalal A. -A. Hawari

Carbonyl and trifluorophosphine adducts of bis(2,4-dimethylpentadienyl)titanium and bis(2,4-dimethylpentadienyl)vanadium Pages 257-263 Richard D. Ernst, Ju-Zheng Liu, David R. Wilson

Highly reduced organometallics : XI. Formal derivatives of the tricarbonylmetallates (6-) of chromium, molybdenum and tungsten Pages 265-276 Gary L. Rochfort, John E. Ellis

Highly reduced organometallics : XII. The reaction of a carbonyltungstate anion with triphenyltin chloride resulting in a phenyl---tin bond cleavage. X-ray structural characterization of the novel salt: [Me4N][(Ph3Sn)2{(Ph2Sn)2O-i-Pr}W(CO)3] Pages 277-290 Gary L. Rochfort, John E. Ellis

Peroxo and alkylperoxidic molybdenum(VI) complexes as intermediates in the epoxidation of olefins by alkyl hydroperoxides Pages 291-310 Patrick Chaumette, Hubert Mimoun, Lucien Saussine, Jean Fischer and, Andre Mitschler

The synthesis and 1H NMR study of vinyl organometallic monomers: (η5-C5H4CH=CH2)M(CO)2(NO) (M = Cr, Mo, W) and (η5-C5H4CH=CH2)M(CO)2 (M = Co, Rh, Ir) Pages 311-318 David W. Macomber, W. Craig Spink, Marvin D. Rausch

Wege und irrwege zu metallorganischen methylen-brücken Pages 319-343 Wolfgang A. Herrmann

Ligand exchange of metal carbonyls by chain mechanisms. Electrochemical kinetics of electron transfer catalysis Pages 345-371 J. W. Hershberger, C. Amatore, J. K. Kochi

Observation and evaluation of the synchronous ligand atom pyramidal inversions in binuclear rhenium carbonyl halide complexes of disulphides and diselenides: an X-ray crystal structure of [Re2Br2(CO)6(C6H5CH2SeSeCH2C6H5)] Pages 373-382 Edward W. Abel, Suresh K. Bhargava, Maqbool M. Bhatti, Muhammed A. Mazid, Keith G. Orrell, Vladimir ik, Michael B. Hursthouse and, K. M. Abdul Malik

Reactions of nitrosonium ion with anionic carbonyl monomers and clusters. Crystal and molecular structure of FeCo2(μ3-NH)(CO)9 Pages 383-394 Douglas E. Fjare, David G. Keyes, Wayne L. Gladfelter

Carbon---hydrogen-transition metal bonds Pages 395-408 Maurice Brookhart, Malcolm L. H. Green

Öffnung einer Fe---Fe-Bindung in [Fe3(CO)9(μ3-SR)]− durch elektrophile reagenzien aus der fünften und sechsten hauptgruppe Pages 409-428 Andreas Winter, Laszlo Zsolnai, Gottfried Huttner

Synthesis of heterometallic cluster compounds from Fe3(μ3-Te)2(CO)9 and comparisons with analogous sulfide clusters Pages 429-438 Leonard E. Bogan Jr., David A. Lesch, Thomas B. Rauchfuss

Asymmetric cyclopalladation in the ferrocene series as a tool for enantioselective synthesis. Preparation of some analogues of natural products Pages 439-446 V. I. Sokolov, L. L. Troitskaya, N. S. Khrushchova

Hetero- and homo-nuclear bimetallic ruthenol complexes by dehydrogenative metallacyclization of Ru(CO)3(bi-1,7-cyclooctadienyl), preparation and x-ray structure of Fe(CO)3(C16H22), RuFe(CO)6(C16H22) and Ru2(CO)6(C16H20) Pages 447-466 Ippei Noda, Hajime Yasuda, Akira Nakamura

Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations Pages 467-483 B. Duane Dombek

Cationic rhodium hydrogenation catalysts containing chelating diphosphine ligands: effect of chelate ring size Pages 485-490 Clark R. Landis, Jack Halpern

On hydrogen activation in the hydroformylation of olefins with Rh4(CO)12 or Co2(CO)8 as catalyst precursors Pages 491-497 Piero Pino, Felix Oldani, Giambattista Consiglio

Oxidative addition of dialkylphosphites to complexes of iridium(I) and rhodium(I) Pages 499-508 M. A. Bennett, T. R. B. Mitchell

The terminations step in palladium-catalyzed insertion reactions Pages 509-515 Marta Catellani, Gian Paolo Chiusoli

Strukturdynamische organometall-komplexe : III. Synthese, struktur und bindungsverhältnisse der komplexe (η5-C5H5)Pd(η1-C5H5)PR3 Pages 517-536 Helmut Werner, Hans-Juergen Kraus, Ulrich Schubert and, Klaus Ackermann, Peter Hofmann

Reactivity of cyclopalladated compounds : VIII. Synthesis of cyclometallated compounds with an oxygen as the donor atom. Crystal and molecular structure of (8-methylquinoline-C,N)-(1-methoxynaphthalene-8-C,O)palladium(II) Pages 537-550 J. Dehand, A. Mauro, H. Ossor, M. Pfeffer, R. H. de A. Santos and, J. R. Lechat

The cross-coupling reactions of organic halides with organic derivatives of tin, mercury and copper catalyzed by palladium Pages 551-564 I. P. Beletskaya

Mechanisms of nucleophilic and electrophilic attack on carbon bonded palladium(II) and platinum(II) complexes Pages 565-587 U. Belluco, R. A. Michelin, P. Uguagliati, B. Crociani

Synthetic and spectroscopic studies of some mono-hydrido-bridged complexes of platinum(II) Pages 589-608 D. Carmona, R. Thouvenot, L. M. Venanzi, F. Bachechi and, L. Zambonelli

Metallierungsreaktionen an cyclometallierten komplexen des typs R2)2(M = Pd, Pt) Pages 609-616 Hans-Peter Abicht, Peter Lehniger, Kurt Issleib

Transition metal---carbon bonds : LV. Cyclometallation and other reactions of PBut2Bui and PPh2Bui with platinum(II) and palladium(II) Pages 617-626 Andrew R. H. Bottomley, Christopher Crocker, Bernard L. Shaw

Cluster chemistry : XVI. Synthesis and crystal structure of AuFe3(μ3-HC=NBut)(CO)9(PPh3), an AuFe3 butterfly cluster Pages 627-638 Michael I. Bruce, Brian K. Nicholson

Issue 2, Pages 639-759 (12 July 1983)

Cumulative author index Pages 639-661

Cumulative subject index Pages 663-759